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src="https://omo-oss-image.thefastimg.com/portal-saas/new2022080310181462570/cms/image/6a8a05f0-0c21-47c5-82c3-12f184865b68.jpg" style="width: 600px; height: 481px;" /></div> <div> </div> <div><span style="color:#6cc9f2;"><span style="font-size:18px;"><strong>一、概述</strong></span></span></div> <div> </div> <div>Hastelloy C-276是一種含鎢的鎳鉻鉬合金，其硅、碳的含量極低。</div> <div>Hastelloy C-276的特點(diǎn)是：</div> <div>●在氧化和還原狀態(tài)下，對大多數腐蝕介質(zhì)具有優(yōu)異的耐腐蝕性。</div> <div>●出色的耐點(diǎn)腐蝕、縫隙腐蝕和應力腐蝕開(kāi)裂性能。</div> <div>Hastelloy C-276的應用領(lǐng)域：</div> <div>在化工和石化領(lǐng)域得到了廣泛的應用，如應用在接觸含氯化物有機物的元件和催化系統中。這種材料尤其適合在高溫、混有雜質(zhì)</div> <div>的無(wú)機酸和有機酸（如甲酸和乙酸）、海水腐蝕環(huán)境中使用。</div> <div>其它應用領(lǐng)域：</div> <div>●紙漿和造紙工業(yè)，如煮解和漂白容器</div> <div>●FGD系統中的洗滌塔、再加熱器、濕汽風(fēng)扇等</div> <div>●在酸性氣體環(huán)境中作業(yè)的設備和元件</div> <div>●乙酸和酸性產(chǎn)品的反應器</div> <div>●硫酸冷凝器</div> <div>●亞甲二苯異氰酸鹽（MDI）</div> <div>●不純磷酸的生產(chǎn)和加工</div> <div> </div> <div><strong>Hastelloy C-276牌號和標準：</strong></div> <div><img class="imageResponse js-onerror" domain-src="/repository/image/f9_Jb6pvTVeNHjn3RSAjaA.jpg" id="124" src="https://omo-oss-image.thefastimg.com/portal-saas/new2022080310181462570/cms/image/42c30dc3-7e47-4a47-b09a-7158d55708d5.jpg" /></div> <div> </div> <div><strong>Hastelloy C-276化學(xué)成分：</strong></div> <div><img class="imageResponse js-onerror" domain-src="/repository/image/jJHEe_t9SwGbroZ2cW74Zw.jpg" id="125" src="https://omo-oss-image.thefastimg.com/portal-saas/new2022080310181462570/cms/image/e05fbafd-acbf-4a83-8aa7-0008e9d0370c.jpg" /></div> <div>Hastelloy C-276物理性能：</div> <div>密度：ρ=8.9g/cm3 熔化溫度范圍：1325～1370℃</div> <div>Hastelloy C-276機械性能：</div> <div>下表中的最小值是標定尺寸規格試樣（固溶處理態(tài)）的縱向和橫向上測得的數據，特殊規格產(chǎn)品及特殊材料性能可以按客戶(hù)需求</div> <div>定制。</div> <div>Hastelloy C-276ISO-V 缺口試驗：</div> <div>平均值 ≥120J/cm2 室溫</div> <div>≥120J/cm2 -196℃</div> <div>Hastelloy C-276金相結構：</div> <div>Hastelloy C-276為面心立方晶格結構，其化學(xué)成分保證了金相穩定性和抗敏化性。</div> <div>Hastelloy C-276耐腐蝕性：</div> <div>較高的鉬、鉻含量使Hastelloy C-276合金能夠抵抗各種化學(xué)介質(zhì)的侵蝕，包括還原性介質(zhì)，如磷酸、鹽酸、硫酸、氯氣、有機</div> <div>或無(wú)機的含氯介質(zhì)。由于鎳含量較高，Hastelloy C-276能有效的抵抗由于氯導致的應力腐蝕開(kāi)裂，甚至是熱的氯化物溶液。</div> <div>時(shí)間-溫度-敏化曲線(xiàn)(含碳量0.008%，參照ASTM G28 方法A)</div> <div><img class="imageResponse js-onerror" domain-src="/repository/image/BaBl2PbNSFO-9SYZ9i3pIg.jpg" id="126" src="https://omo-oss-image.thefastimg.com/portal-saas/new2022080310181462570/cms/image/5d890b75-1fc3-4062-aa00-cdaa434f865e.jpg" /></div> <div>Hastelloy C-276應用范圍：</div> <div>Hastelloy C-276在大多數化工領(lǐng)域和高溫環(huán)境中得到了廣泛的應用。</div> <div>典型應用領(lǐng)域：</div> <div>●煙氣脫硫系統</div> <div>●酸洗和酸再生工廠(chǎng)</div> <div>●乙酸和農用化學(xué)品生產(chǎn)</div> <div>●二氧化鈦生產(chǎn)（氯法）</div> <div>●電解電鍍</div> <div>Hastelloy C-276加工和熱處理：</div> <div>1.HastelloyC-276合金可以通過(guò)傳統生產(chǎn)工藝制造和加工。</div> <div>2.在熱處理之前及熱處理過(guò)程中應始終保持工件清潔和無(wú)污染。</div> <div>3.應充分考慮到該合金在1000℃～600℃間快速冷卻時(shí)對敏化的敏感性。</div> <div>4.在熱處理過(guò)程中不能接觸硫、磷、鉛及其它低熔點(diǎn)金屬，否則會(huì )損害合金的性能，應注意清除諸如標記漆、溫度指示漆、彩色</div> <div>蠟筆、潤滑油、燃料等污物。</div> <div>5.燃料中的含硫量越低越好，天然氣中的硫含量應少于0.1%，重油中硫含量應少于0.5%。</div> <div>6.加熱爐的爐氣以中性至微氧化性為宜，應避免爐氣在氧化性和還原性之間波動(dòng)，加熱火焰不能直接燒向工件。</div> <div>Hastelloy C-276加熱：</div> <div>在熱處理之前及熱處理過(guò)程中應始終保持工件清潔和無(wú)污染。</div> <div>在熱處理過(guò)程中不能接觸硫、磷、鉛及其它低熔點(diǎn)金屬，否則Nicrofer 6616 hMo合金會(huì )變脆，應注意清除諸如標記漆、溫度指</div> <div>示漆、彩色蠟筆、潤滑油、燃料等污物。燃料中的含硫量越低越好，天然氣中的硫含量應少于0.1%，重油中硫含量應少于</div> <div>0.5%。電爐加熱是較好的選擇，因為電爐可以精確控溫，爐氣干凈。若燃氣爐的爐氣足夠純凈，也可以選擇。</div> <div>加熱爐的爐氣以中性至微還原性為宜，應避免爐氣在氧化性和還原性之間波動(dòng)，加熱火焰不能直接燒向工件。</div> <div>Hastelloy C-276熱加工：</div> <div>1.HastelloyC-276的熱加工溫度范圍1200℃～950℃，冷卻方式為水冷或快速空冷。</div> <div>2.為保證最佳的防腐性能，熱加工后應進(jìn)行熱處理，工件應直接加入已升溫的熱處理爐。</div> <div>Hastelloy C-276冷加工：</div> <div>1.Hastelloyc-276的加工硬化率大于奧氏體不銹鋼，因此需要對加工設備進(jìn)行挑選。工件應為固溶熱處理態(tài)，并且在冷軋過(guò)程中</div> <div>應有中間退火。</div> <div>2.若冷軋變形量大于15%，則需要對工件進(jìn)行二次固溶處理。</div> <div>Hastelloy C-276熱處理：</div> <div>1.Hastelloyc-276的固溶處理溫度范圍是1100℃～1160℃。</div> <div>2.冷卻方式為水淬，厚度小于1.5mm 的材料也可采用快速空冷。若采用空冷，則應在2 分鐘內從1000℃冷卻至600℃。</div> <div>3.在熱處理過(guò)程中，必須保持工件清潔。</div> <div>Hastelloy C-276去氧化皮：</div> <div>1.Hastelloyc-276的表面氧化物和焊縫周?chē)暮冈母街?zhù)性比不銹鋼更強，推薦使用細晶砂帶或細晶砂輪進(jìn)行打磨。</div> <div>2.在用HNO3/HF混合酸進(jìn)行酸洗前必須噴砂或打磨將氧化膜打碎。</div> <div>Hastelloy C-276機加工：</div> <div>由于對加工硬化敏感，因此宜采用低切削速度和重進(jìn)刀進(jìn)行加工，才能車(chē)入已冷作硬化的表層下面。</div> <div>Hastelloy C-276焊接：</div> <div>在對鎳基材料進(jìn)行焊接時(shí)，應遵循以下規程：</div> <div>1.工作場(chǎng)地工作場(chǎng)地應單獨分開(kāi)或與碳鋼的加工區域有足夠遠的距離，盡可能保持清潔，設有隔板并避免兩區域間通風(fēng)。</div> <div>2.工作服和輔助用品應佩戴干凈的細紋皮手套，穿著(zhù)干凈的工作服。</div> <div>3.工具和機器設備應該有鎳基合金和鎳鉻鋼的專(zhuān)用工具，鋼絲刷應采用不銹鋼材料制成，機器設備如剪切機、沖床、軋機等應該</div> <div>蓋上氈、紙板或塑料紙以防鐵碳金屬掉在機器表面而使加工材料粘上，導致腐蝕。</div> <div>Hastelloy C-276 清理</div> <div>待焊接的材料應為固溶處理態(tài)，去除氧化皮、油污和各種標記印痕，并用丙酮對焊接區域的基體金屬和填充合金（如焊條）進(jìn)行</div> <div>清潔，注意不能使用三氯乙烯TRI、全氯乙烯PER和四氯化物TETRA。</div> <div>Hastelloy C-276 邊緣準備</div> <div>最好采用機加工，如車(chē)、銑、刨，也可以進(jìn)行等離子切割，若采用后者，切割邊緣（焊接面）一定要研磨干凈平整，允許不過(guò)熱</div> <div>的精磨。</div> <div>Hastelloy C-276 坡口角度</div> <div>與碳鋼相比，鎳基合金和特種不銹鋼的物理性能特點(diǎn)主要是低的熱導率和高的膨脹系數，這些特性都要在焊接坡口準備時(shí)予以考</div> <div>慮，包括加寬底部間隙（1～3mm），同時(shí)由于熔融金屬的粘滯性，在對接焊時(shí)應采用更大的坡口角度（60～70°）以抵消材料</div> <div>的收縮。</div> <div>Hastelloy C-276 起弧</div> <div>不能在工件表面起弧，應在焊接面起弧，以防起弧點(diǎn)導致腐蝕。</div> <div>Hastelloy C-276 焊接工藝</div> <div>Hastelloyc-276適合采用任何傳統焊接工藝焊接，如鎢電極惰性氣體保護焊、等離子弧焊、手工亞弧焊、金屬極惰性氣體保護</div> <div>焊、熔化極惰性氣體保護焊。</div> <div>Hastelloy C-276 填充金屬</div> <div>通常選用的填充金屬</div> <div>Nicrofer S 5923-FM59</div> <div>W.-Nr. 2.4607</div> <div>SG-NiCr23Mo16</div> <div>AWS A5.14 ENiCrMo-13</div> <div>藥皮焊條</div> <div>W.-Nr. 2.4609</div> <div>EL-NiCr22Mo16</div> <div>AWS A5.11 ENiCrMo-13</div> <div>Hastelloy C-276 焊接參數及影響（熱輸入量）</div> <div>焊接操作應在規定的低熱量輸入下進(jìn)行，層間溫度不超過(guò)120℃，并采用窄焊道技術(shù)，注意正確選擇電焊絲和電焊條的直徑（請</div> <div>咨詢(xún)我們的焊接實(shí)驗室）根據這些原理，可以控制焊接參數并得到表-8 所示的單位長(cháng)度的熱量輸入。</div> <div>Hastelloy C-276 焊后處理（酸洗及刷除氧化物）</div> <div>若沒(méi)有特別要求或規定，酸洗通常是焊接中的最后一道工序，一般情況下酸洗由專(zhuān)業(yè)工廠(chǎng)完成。若工件質(zhì)量要求極高，焊完后，</div> 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